High temperature always flows from a hot substance to a cooler substance; that is from higher temperatures to lower temperatures. Quicker-moving molecules impart a little of their power to slower-moving molecules.
Therefore, the earlier molecules slow a small and the slower one moves a small faster.
Sometimes, however, the molecules instead of moving slower or earlier modify their form. The change in form is caused by one or more of the atoms in the molecules shifting to a different location and this shift in the atomic structure of the molecule may cause it to modify from a gas to a liquid or vice versa.
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Basics of Refrigeration